Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan province, College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, Hainan Province, P.R. China.
Org Biomol Chem. 2019 Jan 23;17(4):830-834. doi: 10.1039/c8ob02800a.
A metal-free direct sulfenylation of phenol and arylamine derivatives with various heterocyclic thiols and thiones using a cross dehydrogenative coupling protocol in water at room temperature has been developed. In addition, this chemical method has several advantages including odorless sulfur sources, good functional group tolerance, green solvent, and mild conditions, making it more environmentally friendly.
一种在水中、室温下通过交叉脱氢偶联反应，用各种杂环硫醇和硫酮对酚和芳胺衍生物进行无金属直接磺化的方法已经被开发出来。此外，这种化学方法具有许多优点，包括无臭的硫源、良好的官能团耐受性、绿色溶剂和温和的条件，使其更加环保。
