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用于催化的二维早期过渡金属碳化物(MXenes)

2D Early Transition Metal Carbides (MXenes) for Catalysis.

作者信息

Li Zhe, Wu Yue

机构信息

Department of Chemical and Biological Engineering, Iowa State University, Ames, IA, 50011, USA.

出版信息

Small. 2019 Jul;15(29):e1804736. doi: 10.1002/smll.201804736. Epub 2019 Jan 22.

Abstract

MXenes, a bourgeoning class of 2D transition metal carbides, are of considerable interest in catalysis due to their rich surface chemistry, tunable electronic structures, and thermal stability. Here, recent conceptual advances in applying MXenes and their nanocomposites in (photo)electrocatalysis and conventional heterogeneous catalysis are highlighted. In addition, the nature of active sites in the MXene-based catalysts are discussed and the significance and challenges in the future development of catalysts using MXenes as the platforms are summarized.

摘要

MXenes是一类新兴的二维过渡金属碳化物,由于其丰富的表面化学性质、可调节的电子结构和热稳定性,在催化领域备受关注。本文重点介绍了将MXenes及其纳米复合材料应用于(光)电催化和传统多相催化的最新概念进展。此外,还讨论了基于MXene的催化剂中活性位点的性质,并总结了以MXenes为平台的催化剂未来发展的意义和挑战。

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