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硅晶体平面的演变——在25重量%的四甲基氢氧化铵中对正方形和圆形图案的蚀刻

Evolution of Si Crystallographic Planes-Etching of Square and Circle Patterns in 25 wt % TMAH.

作者信息

Smiljanić Milče M, Lazić Žarko, Radjenović Branislav, Radmilović-Radjenović Marija, Jović Vesna

机构信息

Institute of Chemistry, Technology and Metallurgy-Centre of Microelectronic Technologies (IHTM-CMT), University of Belgrade, Njegoševa 12, 11000 Belgrade, Serbia.

Institute of Physics, University of Belgrade, Pregrevica 118, 11080 Belgrade, Serbia.

出版信息

Micromachines (Basel). 2019 Jan 31;10(2):102. doi: 10.3390/mi10020102.

DOI:10.3390/mi10020102
PMID:30708946
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6412402/
Abstract

Squares and circles are basic patterns for most mask designs of silicon microdevices. Evolution of etched Si crystallographic planes defined by square and circle patterns in the masking layer is presented and analyzed in this paper. The sides of square patterns in the masking layer are designed along predetermined crystallographic directions. Etching of a (100) silicon substrate is performed in 25 wt % tetramethylammonium hydroxide (TMAH) water solution at the temperature of 80 °C. Additionally, this paper presents three-dimensional (3D) simulations of the profile evolution during silicon etching of designed patterns based on the level-set method. We analyzed etching of designed patterns in the shape of square and circle islands. The crystallographic planes that appear during etching of 3D structures in the experiment and simulated etching profiles are determined. A good agreement between dominant crystallographic planes through experiments and simulations is obtained. The etch rates of dominant exposed crystallographic planes are also analytically calculated.

摘要

正方形和圆形是大多数硅微器件掩膜设计的基本图案。本文展示并分析了由掩膜层中的正方形和圆形图案所定义的蚀刻硅晶体平面的演变。掩膜层中正方形图案的边是沿着预定的晶体学方向设计的。在80°C的温度下,在25 wt%的四甲基氢氧化铵(TMAH)水溶液中对(100)硅衬底进行蚀刻。此外,本文基于水平集方法给出了设计图案在硅蚀刻过程中轮廓演变的三维(3D)模拟。我们分析了正方形和圆形岛状设计图案的蚀刻情况。确定了实验中3D结构蚀刻过程中出现的晶体平面以及模拟蚀刻轮廓。通过实验和模拟在主要晶体平面方面获得了良好的一致性。还对主要暴露晶体平面的蚀刻速率进行了分析计算。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/84a923c91b8c/micromachines-10-00102-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/1ca617ba5004/micromachines-10-00102-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/e893c70275ff/micromachines-10-00102-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/874ee7398f11/micromachines-10-00102-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/d6c59860617a/micromachines-10-00102-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/b511f65b31a6/micromachines-10-00102-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/25d0543c8c0b/micromachines-10-00102-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/394109155a14/micromachines-10-00102-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/a9addd34b0e7/micromachines-10-00102-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/84a923c91b8c/micromachines-10-00102-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/1ca617ba5004/micromachines-10-00102-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/e893c70275ff/micromachines-10-00102-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/874ee7398f11/micromachines-10-00102-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/d6c59860617a/micromachines-10-00102-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/b511f65b31a6/micromachines-10-00102-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/25d0543c8c0b/micromachines-10-00102-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/394109155a14/micromachines-10-00102-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/a9addd34b0e7/micromachines-10-00102-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c988/6412402/84a923c91b8c/micromachines-10-00102-g009.jpg

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Level set approach to anisotropic wet etching of silicon.水平集方法用于各向异性硅的湿法刻蚀。
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微机电系统/纳米机电系统传感器特刊编辑:制造与应用
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