通过光氧化还原催化实现烯键的分子间、氧化还原中性叠氮芳基化。
Intermolecular, redox-neutral azidoarylation of alkenes via photoredox catalysis.
机构信息
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China.
出版信息
Chem Commun (Camb). 2019 Feb 19;55(16):2336-2339. doi: 10.1039/c9cc00241c.
An intermolecular, redox-neutral azidoarylation of alkenes with pyridines and TMSN3 has been reported via visible light-induced photoredox catalysis. This protocol utilized a radical addition/radical coupling sequence, allowing for facile and regioselective installation of versatile β-azido pyridines under redox-neutral and mild conditions.
通过可见光诱导光氧化还原催化，报道了一种分子间、氧化还原中性的叠氮芳基化反应，其中包括烯烃、吡啶和 TMSN3。该反应方案利用自由基加成/自由基偶联序列，在氧化还原中性和温和条件下，可方便地、区域选择性地引入多功能的β-叠氮吡啶。
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