Liu Liu Leo, Stephan Douglas W
Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario M5S3H6, Canada.
Chem Soc Rev. 2019 Jul 1;48(13):3454-3463. doi: 10.1039/c8cs00940f.
While conventional approaches to stabilizing main group radicals have involved the use of Lewis acids or bases, this tutorial review focuses on new avenues to main group radicals derived from combinations of donor and acceptor molecules. Reactions involving the use of both classical Lewis acid-base adducts and frustrated Lewis pair systems are discussed and the subsequent reactivity is considered.
虽然稳定主族自由基的传统方法涉及使用路易斯酸或碱，但本教程综述重点关注从供体和受体分子组合衍生出的主族自由基的新途径。讨论了涉及使用经典路易斯酸碱加合物和受阻路易斯对体系的反应，并考虑了随后的反应活性。
