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电化学研究果壳生物废料衍生的纳米多孔活性炭在超级电容器中的应用。

Electrochemical Studies on Fruit Shell Bio-Waste Derived Nanoporous Activated Carbons for Supercapacitor Applications.

机构信息

Catalysis and Nanomaterials Research Laboratory, Department of Chemistry, Loyola College (Autonomous), Chennai 600034, India.

Materials Division, School of Advanced Sciences, Vellore Institute of Technology (VIT) University, Chennai Campus, Chennai 600127, India.

出版信息

J Nanosci Nanotechnol. 2019 Jun 1;19(6):3388-3397. doi: 10.1166/jnn.2019.16115.

Abstract

Supercapacitors are perfect energy storage devices; they can be charged almost instantly and release energy over a long period. Another advantage of using supercapacitors is their multipletimes chargeable behavior with minimum degradation in performance. Herein, we report the nanoporous activated carbon based modified electrodes prepared by using phosphoric acid (PA) activation method at different temperatures (600, 700, 800, and 900 °C) using bio-waste precursor, () fruit shell. Because of their excellent energy storage capacity, in the present work, supercapacitive behavior of the nanoporous activated carbon based modified electrode has been demonstrated and hence the electrochemical properties of the developed supercapacitor electrodes are analyzed using cyclic voltammetry, galvanostatic charge-discharge measurements, electrochemical impedance spectroscopy and cycling studies using 1 M KOH as the electrolyte. The developed supercapacitor nanoporous activated carbon materials are characterized by X-ray diffraction, functional group analysis, surface area and morphological studies.

摘要

超级电容器是完美的储能设备;它们可以几乎瞬间充电,并在长时间内释放能量。使用超级电容器的另一个优点是,它们可以进行多次充电,而性能下降最小。在此,我们报告了使用生物废料前体 () 果壳,通过不同温度(600、700、800 和 900°C)的磷酸(PA)活化法制备的基于纳米多孔活性炭的改性电极。由于其出色的储能能力,在本工作中,基于纳米多孔活性炭的改性电极的超级电容行为得到了证明,因此使用循环伏安法、恒电流充放电测量、电化学阻抗谱和使用 1 M KOH 作为电解质的循环研究来分析所开发的超级电容器电极的电化学性能。使用 X 射线衍射、官能团分析、表面积和形态研究对开发的超级电容器纳米多孔活性炭材料进行了表征。

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