Su Hongyu, Lan Caining, Wang Zhouping, Zhu Lin, Zhu Mingqiang
College of Mechanical and Electronic Engineering, Northwest A&F University, Yangling 712100, China.
Northwest Research Center of Rural Renewable Energy Exploitation and Utilization of M.O.A, Northwest A&F University, Yangling 712100, China.
Polymers (Basel). 2023 Jan 28;15(3):663. doi: 10.3390/polym15030663.
Activated carbons (ACs) for supercapacitors were synthesized from Eucommia ulmoides Oliver (EUO) wood by HPO with systemic activation processes. The target structure of ACs could be prepared by adjusting the technological parameters. As the HPO concentration was 25%, the mass ratio of feedstocks to activator was 1:4, the activation time was 6 h, and the activation temperature was 400 °C, the obtained AC revealed a high specific surface area (2033.87 m·g) and well-developed mesoporous (the rate of mesoporous was 96.4%) with the best economic feasibility. Besides, it possessed excellent electrochemical performance: the maximum specific capacitance reached up to 252 F·g, the charging and discharging period was 3098.2 s at 0.2 A·g, and the retention rate of specific capacitance reached 92.3% after 10,000 cycles. This low temperature and convenience technology provide a valuable reference for synthesizing the EUO-based ACs, making high-value utilization on the EUO branches, and owning a broad application prospect in supercapacitors.
采用磷酸活化法(HPO),通过系统的活化工艺,以杜仲(EUO)木材为原料合成了用于超级电容器的活性炭(ACs)。通过调整工艺参数可以制备出目标结构的ACs。当磷酸浓度为25%,原料与活化剂的质量比为1:4,活化时间为6小时,活化温度为400℃时,所得AC具有高比表面积(2033.87 m²·g)和发达的中孔结构(中孔率为96.4%),且具有最佳的经济可行性。此外,它还具有优异的电化学性能:最大比电容达到252 F·g,在0.2 A·g电流密度下充放电周期为3098.2秒,经过10000次循环后比电容保持率达到92.3%。这种低温便捷的技术为合成基于杜仲的ACs提供了有价值的参考,实现了杜仲树枝的高值利用,在超级电容器领域具有广阔的应用前景。