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经济杠杆可实现 43%碳排放量的燃烧后捕集:超音速分离器从原始天然气和 CO 干燥中回收甲醇水合物抑制剂。

Economic leverage affords post-combustion capture of 43% of carbon emissions: Supersonic separators for methanol hydrate inhibitor recovery from raw natural gas and CO drying.

机构信息

Escola de Química, Federal University of Rio de Janeiro, Av. Horacio Macedo, 2030, Bl. E, 21949-900, Rio de Janeiro, RJ, Brazil.

出版信息

J Environ Manage. 2019 Apr 15;236:534-550. doi: 10.1016/j.jenvman.2019.02.008. Epub 2019 Feb 13.

Abstract

Offshore oil/gas productions are power intensive and CO emitters from gas-fired power generation. This work investigates supersonic separator as a strategy for affording post-combustion capture backed up by cost reductions. Conventional offshore gas processing usually loses thermodynamic hydrate inhibitor methanol in processing and exported gas. This work analyses a supersonic separator variant gas processing simultaneously reducing methanol losses. Such process dramatically improves gas-plant profitability via cost-reduction of methanol make-up and power-consumption, simultaneously increasing revenues from liquefied-petroleum-gas by-product. This economic leverage affords post-combustion carbon capture, including subsequent CO dehydration and compression for exportation of high-pressure liquid CO. This corresponds to abate 43% of CO emissions boosting revenues via enhanced oil recovery. Moreover, CO is dehydrated via another supersonic separator operating with minimum head-loss, minimizing compression costs. Despite its much higher investment, the new process with carbon capture presents higher net value (865.63 MMUSD) than the conventional processing without carbon capture (829.31 MMUSD), being economically feasible and more environmentally adequate with cleaner natural gas production and successful CO management. The new process is superior in several scenarios and particularly favored by oil prices above 55 USD/bbl. Rising oil price from 40 to 100 USD/bbl, the new process net value rises 29%, whereas the conventional counterpart rises only 7.5%. In addition, as a plausible future scenario, CO taxation favors the new process, which always has superior economic performance, even without CO taxation. In summary, implementing supersonic separators in offshore natural gas processing aiming at anti-hydrate recovery and CO dehydration for enhanced oil recovery creates economic leverage sustaining Carbon Capture & Storage without loss of competitiveness. This result, backed up by rigorous thermodynamic simulations and economic-environmental assessments, configure an original achievement to the literature.

摘要

海上石油/天然气生产是能源密集型的,并且天然气发电会排放 CO。这项工作研究了超音速分离器作为一种策略,为后燃烧捕获提供支持,并降低成本。传统的海上天然气处理通常会在处理和出口气体中失去热力学水合物抑制剂甲醇。这项工作分析了超音速分离器变体的气体处理,同时减少甲醇损失。这种工艺通过减少甲醇补加和电力消耗来降低成本,同时通过液化石油气副产品增加收入,从而极大地提高了气田的盈利能力。这种经济杠杆为后燃烧碳捕获提供了支持,包括随后的 CO 脱水和压缩,以出口高压液体 CO。这相当于减少了 43%的 CO 排放,通过提高石油采收率增加了收入。此外,通过另一个超音速分离器以最小的压降运行来脱水 CO,从而最大限度地降低压缩成本。尽管投资较高,但具有碳捕获功能的新工艺的净现值(865.63 亿美元)高于没有碳捕获功能的传统工艺(829.31 亿美元),新工艺在经济上可行,并且在生产更清洁的天然气和成功管理 CO 方面更能满足环境要求。新工艺在多个场景中都具有优势,特别是在油价高于 55 美元/桶时更为有利。随着油价从 40 美元上涨到 100 美元,新工艺的净现值增长了 29%,而传统工艺仅增长了 7.5%。此外,作为一个合理的未来情景,CO 税有利于新工艺,即使没有 CO 税,新工艺也始终具有优越的经济性能。总之,在海上天然气处理中实施超音速分离器,旨在回收水合物和 CO 脱水以提高石油采收率,为碳捕获和储存创造了经济杠杆,而不会失去竞争力。这项工作得到了严格的热力学模拟和经济环境评估的支持,为文献增添了一项原创成果。

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