Marpaung Freddy, Kim Minjun, Khan Junayet Hossain, Konstantinov Konstantin, Yamauchi Yusuke, Hossain Md Shahriar A, Na Jongbeom, Kim Jeonghun
Australian Institute for Innovative Materials (AIIM), University of Wollongong, North Wollongong, NSW, 2500, Australia.
Australian Institute for Bioengineering and Nanotechnology (AIBN), The University of Queensland, Brisbane, QLD, 4072, Australia.
Chem Asian J. 2019 May 2;14(9):1331-1343. doi: 10.1002/asia.201900026. Epub 2019 Apr 10.
Metal-organic framework (MOF)-derived nanoporous carbon materials have attracted significant interest due to their advantages of controllable porosity, good thermal/chemical stability, high electrical conductivity, catalytic activity, easy modification with other elements and materials, etc. Thus, MOF-derived carbons have been used in numerous applications, such as environmental remediations, energy storage systems (i.e. batteries, supercapacitors), and catalysts. To date, many strategies have been developed to enhance the properties and performance of MOF-derived carbons. Herein, we introduce and summarize recent important approaches for advanced MOF-derived carbon structures with a focus on precursor control, heteroatom doping, shape/orientation control, and hybridization with other functional materials.
金属有机框架(MOF)衍生的纳米多孔碳材料因其具有孔隙率可控、良好的热/化学稳定性、高导电性、催化活性、易于与其他元素和材料进行改性等优点而备受关注。因此,MOF衍生的碳已被用于众多应用中,如环境修复、储能系统(即电池、超级电容器)和催化剂。迄今为止,已经开发了许多策略来增强MOF衍生碳的性能。在此,我们介绍并总结了用于先进MOF衍生碳结构的近期重要方法,重点关注前驱体控制、杂原子掺杂、形状/取向控制以及与其他功能材料的杂化。