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金属有机骨架衍生碳材料的应用。

Applications of Metal-Organic-Framework-Derived Carbon Materials.

机构信息

School of Chemistry and Chemical Engineering, Institute for Innovative Materials and Energy, Yangzhou University, Yangzhou, 225009, Jiangsu, P. R. China.

出版信息

Adv Mater. 2019 Feb;31(6):e1804740. doi: 10.1002/adma.201804740. Epub 2018 Dec 13.

Abstract

Carbon materials derived from metal-organic frameworks (MOFs) have attracted much attention in the field of scientific research in recent years because of their advantages of excellent electron conductivity, high porosity, and diverse applications. Tremendous efforts are devoted to improving their chemical and physical properties, including optimizing the morphology and structure of the carbon materials, compositing them with other materials, and so on. Here, many kinds of carbon materials derived from metal-organic frameworks are introduced with a particular focus on their promising applications in batteries (lithium-ion batteries, lithium-sulfur batteries, and sodium-ion batteries), supercapacitors (metal oxide/carbon and metal sulfide/carbon), electrocatalytic reactions (oxygen reduction reaction, oxygen evolution reaction, and hydrogen evolution reaction), water treatment (MOF-derived carbon and other techniques), and other possible fields. To close, some existing problem and corresponding possible solutions are proposed based on academic knowledge from the reported literature, along with a great deal of experimental experience.

摘要

近年来,由于具有优异的导电性、高孔隙率和多样化的应用等优点,金属有机框架(MOF)衍生的碳材料在科学研究领域引起了广泛关注。人们投入了大量精力来改善其化学和物理性质,包括优化碳材料的形态和结构,将其与其他材料复合等。本文主要介绍了多种由金属有机框架衍生的碳材料,特别关注它们在电池(锂离子电池、锂硫电池和钠离子电池)、超级电容器(金属氧化物/碳和金属硫化物/碳)、电催化反应(氧还原反应、氧析出反应和析氢反应)、水处理(MOF 衍生碳和其他技术)和其他可能领域中的应用。最后,根据文献报道的学术知识和大量实验经验,提出了一些现有的问题和相应的可能解决方案。

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