Song Haiyan, Wang Pan, Li Shi, Deng Weiping, Li Yanyun, Zhang Qinghong, Wang Ye
State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Chem Commun (Camb). 2019 Apr 9;55(30):4303-4306. doi: 10.1039/c9cc00619b.
The H2WO4-Pt/ZrO2 combination catalyses the direct conversion of cellulose into ethanol with a yield of 32% in an aqueous medium under H2. H2WO4 mainly facilitates the cleavage of C-C bonds in the glucose unit, while Pt/ZrO2 with an appropriate fraction of Pt0 and Pt2+ promotes the formation of ethanol through a selective C-O bond activation.
H2WO4-Pt/ZrO2组合在氢气存在下于水介质中催化纤维素直接转化为乙醇，产率为32%。H2WO4主要促进葡萄糖单元中碳-碳键的断裂，而具有适当比例Pt0和Pt2+的Pt/ZrO2通过选择性碳-氧键活化促进乙醇的形成。
