Powley Samuel L, Inoue Shigeyoshi
Department of Chemistry, WACKER-Institute of Silicon Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, 85748, Garching bei München, Germany.
Chem Rec. 2019 Nov;19(11):2179-2188. doi: 10.1002/tcr.201800188. Epub 2019 Mar 5.
Donor-stabilised silyliumylidene ions, from the parent [R-Si:] , are a class of low-valent silicon species which have received increasing research interest in the last several years. This interest began in the fundamental synthesis and characterisation of these compounds, but has since started to include more investigation into their further reactivity after several stable NHC-stabilised silyliumylidene ions were reported. This personal account briefly discusses the history of the still-young field of silyliumylidene ions followed by a more detailed discussion of published work from our group on the further development of silyliumylidene chemistry over the last four years.
源自母体[R-Si:]的供体稳定的硅亚烷基离子是一类低价硅物种，在过去几年中受到了越来越多的研究关注。这种关注始于这些化合物的基础合成和表征，但自从报道了几种稳定的NHC稳定的硅亚烷基离子后，对它们进一步反应性的研究也开始增多。这篇个人综述简要讨论了仍处于起步阶段的硅亚烷基离子领域的历史，随后更详细地讨论了我们团队在过去四年中发表的关于硅亚烷基化学进一步发展的工作。
