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碳纳米管 - 氧化铜纳米复合材料作为还原对硝基苯酚的新型催化剂材料的简便制备方法

Facile Preparation of Carbon Nanotube-CuO Nanocomposites as New Catalyst Materials for Reduction of P-Nitrophenol.

作者信息

Feng Yao, Jiao Tifeng, Yin Juanjuan, Zhang Lun, Zhang Lexin, Zhou Jingxin, Peng Qiuming

机构信息

State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, 066004, People's Republic of China.

Hebei Key Laboratory of Applied Chemistry, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, 066004, People's Republic of China.

出版信息

Nanoscale Res Lett. 2019 Mar 5;14(1):78. doi: 10.1186/s11671-019-2914-1.

DOI:10.1186/s11671-019-2914-1
PMID:30838470
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6401016/
Abstract

The effective synthesis and self-assembly of nanocomposites were of key importance for a broad range of nanomaterial applications. In this work, new carbon nanotube (CNT)-CuO nanocomposites were successfully synthesized via a facile approach. CNT was selected as the anchoring substrate to load CuO nanoparticles to prepare composite catalysts with well stability and good reusability. It is discovered that the prepared CNT-CuO nanocomposite materials could be effectively controlled via regulating preparation temperature and time without the use of any stabilizing agents. The nanostructures of synthesized composites were well characterized by many techniques, such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). And the prepared CNT-CuO nanocomposites with optimized preparation conditions as new catalyst displayed excellent catalytic performance on the reduction reaction of p-nitrophenol, demonstrating potential applications for environmental governance and composite materials.

摘要

纳米复合材料的有效合成与自组装对于广泛的纳米材料应用至关重要。在这项工作中,通过一种简便的方法成功合成了新型碳纳米管(CNT)-氧化铜(CuO)纳米复合材料。选择碳纳米管作为锚定基质来负载氧化铜纳米颗粒,以制备具有良好稳定性和高可重复使用性的复合催化剂。研究发现,通过调节制备温度和时间,无需使用任何稳定剂即可有效控制所制备的碳纳米管-氧化铜纳米复合材料。通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)和X射线衍射(XRD)等多种技术对合成复合材料的纳米结构进行了很好的表征。并且,所制备的具有优化制备条件的碳纳米管-氧化铜纳米复合材料作为新型催化剂,在对硝基苯酚的还原反应中表现出优异的催化性能,展示了其在环境治理和复合材料方面的潜在应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7311/6401016/3d05987bb747/11671_2019_2914_Fig7_HTML.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7311/6401016/7ea613f55cc6/11671_2019_2914_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7311/6401016/156d2f022154/11671_2019_2914_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7311/6401016/3d05987bb747/11671_2019_2914_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7311/6401016/ca53228ce7dc/11671_2019_2914_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7311/6401016/2fdb41099dc8/11671_2019_2914_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7311/6401016/ed44ff75946b/11671_2019_2914_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7311/6401016/8ad6671e5528/11671_2019_2914_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7311/6401016/7ea613f55cc6/11671_2019_2914_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7311/6401016/156d2f022154/11671_2019_2914_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7311/6401016/3d05987bb747/11671_2019_2914_Fig7_HTML.jpg

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