Synthesis of β-Sulfonyl Amides through a Multicomponent Reaction with the Insertion of Sulfur Dioxide under Visible Light Irradiation.

A multicomponent reaction of styrenes, aryldiazonium tetrafluoroborates, sulfur dioxide, nitriles, and water in the presence of a photocatalyst at room temperature is performed. This vicinal aminosulfonylation of styrenes with the insertion of sulfur dioxide under visible light irradiation proceeds efficiently with excellent chemoselectivity, giving rise to the corresponding β-sulfonyl amides in moderate to good yields.