Advanced Functional Materials Team, Research Center for Photovoltaics (RCPV), National Institute of Advanced Industrial Science and Technology (AIST), Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
Chem Commun (Camb). 2019 Mar 26;55(26):3813-3816. doi: 10.1039/c9cc01061k.
The high-value-added chemical reagent peroxydisulfate (S2O82-) was produced photocatalytically over noble-metal loaded WO3 powder suspensions in aqueous H2SO4 under flowing O2 and simulated solar light irradiation. Pt cocatalyst showed the highest photocatalytic activity for S2O82- formation of the studied metals (Au, Pd, Rh, and Ru). Further study indicated that continuous accumulation of S2O82- was achieved only over the Pt/WO3 photocatalyst.
在流动的 O2 和模拟太阳光照射下，贵金属负载 WO3 粉末悬浮液在水中将高附加值的化学试剂过二硫酸盐（S2O82-）光催化合成。Pt 助催化剂表现出对所研究金属（Au、Pd、Rh 和 Ru）中 S2O82-形成的最高光催化活性。进一步的研究表明，只有在 Pt/WO3 光催化剂上才能实现 S2O82-的连续积累。
