Tu Wenmao, Bai Ziyu, Deng Zhao, Zhang Haining, Tang Haolin
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China.
Nanomaterials (Basel). 2019 Mar 14;9(3):432. doi: 10.3390/nano9030432.
As an important component, the anode determines the property and development of lithium ion batteries. The synthetic method and the structure design of the negative electrode materials play decisive roles in improving the property of the thus-assembled batteries. Si@C compound materials have been widely used based on their excellent lithium ion intercalation capacity and cyclic stability, in which the in-situ synthetic method can make full use of the structural advantages of the monomer itself, thus improving the electrochemical performance of the anode material. In this paper, the different preparation technologies and composite structures of Si@C compound materials by in-situ synthesis are introduced. The research progress of Si@C compound materials by in-situ synthesis is reviewed, and the prospect of future development of Si@C compound materials has been tentatively commented.
作为一个重要组成部分,阳极决定了锂离子电池的性能和发展。负极材料的合成方法和结构设计在提高由此组装的电池性能方面起着决定性作用。Si@C复合材料因其优异的锂离子嵌入能力和循环稳定性而被广泛应用,其中原位合成方法可以充分利用单体本身的结构优势,从而提高负极材料的电化学性能。本文介绍了通过原位合成制备Si@C复合材料的不同技术和复合结构。综述了原位合成Si@C复合材料的研究进展,并对Si@C复合材料未来的发展前景进行了初步评述。