Gui Jiao, Xie Haisheng, Jiang Huanfeng, Zeng Wei
Key Laboratory of Functional Molecular Engineering of Guangdong Province, Guangdong Engineering Research Center for Green Fine Chemicals, School of Chemistry and Chemical Engineering , South China University of Technology , Guangzhou 510641 , China.
Org Lett. 2019 Apr 19;21(8):2804-2807. doi: 10.1021/acs.orglett.9b00786. Epub 2019 Apr 4.
Visible-light-induced cross-coupling of arylsulfonyl azides with tertiaryamines in the presence of Eosin Y at room temperature has been achieved. This transformation features alkyl C-C bond cleavage and provides a green approach to N-sulfonylamidines under mild conditions.
在室温下，曙红Y存在时，实现了可见光诱导芳基磺酰叠氮与叔胺的交叉偶联。这种转化具有烷基C-C键断裂的特点，并在温和条件下为N-磺酰脒提供了一种绿色合成方法。
