Zhang Qingfa, Yi Weiming, Li Zhihe, Wang Lihong, Cai Hongzhen
School of Agricultural and Food Engineering, Shandong University of Technology, Zibo 255000, China.
Shandong Research Center of Engineering and Technology for Clean Energy, Zibo 255000, China.
Polymers (Basel). 2018 Mar 8;10(3):286. doi: 10.3390/polym10030286.
Rice husk biochar was utilized to reinforce high-density polyethylene (HDPE) and to prepare biochar/plastic composites (BPC) by the extrusion method. Morphologies, non-isothermal crystallization behavior, and mechanical properties of the composites were investigated. The SEM (scanning electron microscope) showed that HDPE was embedded into the holes of the rice husk biochar. The DSC (differential scanning calorimeter) showed that biochar could reduce the crystallization rate and the higher the content of rice husk biochar, the slower the crystallization rate. Significantly, the bending and tensile strength of BPC could reach 53.7 and 20 MPa, far beyond WPC (wood plastic composites). With the increase of filler content, BPC were still stronger than WPC, although the impact strength of BPC and WPC all showed a general decline in the trend. The strong interaction was achieved by the utilization of rice husk biochar to reinforce HDPE.
稻壳生物炭被用于增强高密度聚乙烯(HDPE),并通过挤出法制备生物炭/塑料复合材料(BPC)。研究了复合材料的形态、非等温结晶行为和力学性能。扫描电子显微镜(SEM)显示HDPE嵌入到稻壳生物炭的孔中。差示扫描量热仪(DSC)表明生物炭会降低结晶速率,且稻壳生物炭含量越高,结晶速率越慢。值得注意的是,BPC的弯曲强度和拉伸强度分别可达53.7和20MPa,远超木塑复合材料(WPC)。随着填料含量的增加,尽管BPC和WPC的冲击强度均呈总体下降趋势,但BPC仍比WPC更坚固。通过利用稻壳生物炭增强HDPE实现了强相互作用。