Chen Jinxiang, Wang Yong, Gu Chenglong, Liu Jianxun, Liu Yufu, Li Min, Lu Yun
Key Laboratory of Concrete and Prestressed Concrete Structures of Ministry of Education & International Institute for Urban Systems Engineering, Southeast University, Nanjing 210096, China.
Faculty of Mechanical Engineering & Automation, Zhejiang Sci-Tech University, Hangzhou 310018, China.
Materials (Basel). 2013 Jun 18;6(6):2483-2496. doi: 10.3390/ma6062483.
This study investigated the mechanisms, using microscopy and strength testing approaches, by which the addition of maleic anhydride grafted high-density polyethylene (MAPE) enhances the mechanical properties of basalt fiber-wood-plastic composites (BF-WPCs). The maximum values of the specific tensile and flexural strengths are achieved at a MAPE content of 5%-8%. The elongation increases rapidly at first and then continues slowly. The nearly complete integration of the wood fiber with the high-density polyethylene upon MAPE addition to WPC is examined, and two models of interfacial behavior are proposed. We examined the physical significance of both interfacial models and their ability to accurately describe the effects of MAPE addition. The mechanism of formation of the Model I interface and the integrated matrix is outlined based on the chemical reactions that may occur between the various components as a result of hydrogen bond formation or based on the principle of compatibility, resulting from similar polarity. The Model I fracture occurred on the outer surface of the interfacial layer, visually demonstrating the compatibilization effect of MAPE addition.
本研究采用显微镜和强度测试方法,探究了添加马来酸酐接枝高密度聚乙烯(MAPE)提高玄武岩纤维-木塑复合材料(BF-WPC)力学性能的机制。当MAPE含量为5%-8%时,比拉伸强度和比弯曲强度达到最大值。伸长率起初迅速增加,然后缓慢持续增加。研究了在木塑复合材料中添加MAPE后木纤维与高密度聚乙烯几乎完全融合的情况,并提出了两种界面行为模型。我们研究了两种界面模型的物理意义及其准确描述添加MAPE效果的能力。基于各组分之间可能因氢键形成而发生的化学反应,或基于相似极性导致的相容性原理,概述了模型I界面和整合基体的形成机制。模型I断裂发生在界面层的外表面,直观地证明了添加MAPE的增容效果。