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用于将太阳光电磁波转换为电能的聚合物材料。

Polymeric Materials for Conversion of Electromagnetic Waves from the Sun to Electric Power.

作者信息

Haque S K Manirul, Ardila-Rey Jorge Alfredo, Umar Yunusa, Rahman Habibur, Mas'ud Abdullahi Abubakar, Muhammad-Sukki Firdaus, Albarracín Ricardo

机构信息

Department of Chemical and Process Engineering Technology, Jubail Industrial College, P.O. Box 10099, Jubail 31961, Saudi Arabia.

Department of Electrical Engineering, Universidad Técnica Federico Santa María, Santiago de Chile 8940000, Chile.

出版信息

Polymers (Basel). 2018 Mar 12;10(3):307. doi: 10.3390/polym10030307.

Abstract

Solar photoelectric energy converted into electricity requires large surface areas with incident light and flexible materials to capture these light emissions. Currently, sunlight rays are converted to electrical energy using silicon polymeric material with efficiency up to 22%. The majority of the energy is lost during conversion due to an energy gap between sunlight photons and polymer energy transformation. This energy conversion also depends on the morphology of present polymeric materials. Therefore, it is very important to construct mechanisms of highest energy occupied molecular orbitals (HOMO)s and the lowest energy unoccupied molecular orbitals (LUMO)s to increase the efficiency of conversion. The organic and inorganic solar cells used as dyes can absorb more photons from sunlight and the energy gap will be less for better conversion of energy to electricity than the conventional solar cells. This paper provides an up-to-date review on the performance, characterization, and reliability of different composite polymeric materials for energy conversion. Specific attention has been given to organic solar cells because of their several advantages over others, such as their low-energy payback time, conversion efficiency and greenhouse emissions. Finally, this paper provides the recent progress on the application of both organic and inorganic solar cells for electric power generations together with several challenges that are currently faced.

摘要

太阳能转化为电能需要大面积的受光表面和柔性材料来捕获这些光发射。目前,利用硅聚合物材料将太阳光转化为电能,效率高达22%。由于太阳光光子与聚合物能量转换之间存在能隙,大部分能量在转换过程中损失。这种能量转换还取决于现有聚合物材料的形态。因此,构建最高占据分子轨道(HOMO)和最低未占据分子轨道(LUMO)的机制以提高转换效率非常重要。用作染料的有机和无机太阳能电池比传统太阳能电池能吸收更多来自太阳光的光子,并且能隙更小,从而能更好地将能量转化为电能。本文对不同复合聚合物材料用于能量转换的性能、表征和可靠性进行了最新综述。由于有机太阳能电池相对于其他电池具有诸多优势,如低能量回收期、转换效率和温室气体排放等,因此对其给予了特别关注。最后,本文介绍了有机和无机太阳能电池在发电应用方面的最新进展以及目前面临的若干挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7db8/6415068/5c6bb27a99fc/polymers-10-00307-g001.jpg

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