一种基于醌顺式烯基锁的可见光脱笼通用策略。
A general strategy for visible-light decaging based on the quinone cis-alkenyl lock.
作者信息
Walton David P, Dougherty Dennis A
机构信息
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA.
出版信息
Chem Commun (Camb). 2019 Apr 23;55(34):4965-4968. doi: 10.1039/c9cc01073d.
PMID:30968102
Abstract
Combining the fast thermal cyclization of o-coumaric acid derivatives with the intramolecular photoreduction of quinones gives new visible-light photoremovable protecting groups absorbing well above 450 nm.
摘要
将邻香豆酸衍生物的快速热环化与醌的分子内光还原相结合，可得到吸收波长远高于450nm的新型可见光光可去除保护基团。
Zotero 插件