Wu Ying, Wang Jixiao, Ou Bin, Zhao Song, Wang Zhi
CERC, School of Chemical Engineering and Technology Tianjin University, Tianjin 300354, China.
Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin University, Tianjin 300354, China.
Polymers (Basel). 2019 Apr 15;11(4):681. doi: 10.3390/polym11040681.
One-dimensional polyaniline nano-materials (1-D nano-PANI) have great promise applications in supercapacitors, sensors and actuators, electrochromic devices, anticorrosive coatings, and other nanometer devices. Consequently, commercial production of 1-D nano-PANI at large-scale needs to be quickly developed to ensure widespread usage of this material. Until now, approaches-including hard template methods, soft template methods, interfacial polymerization, rapid mixing polymerization, dilute polymerization, and electrochemical polymerization-have been reported to be used to preparation of this material. Herein, some important issues dealing with commercial production of 1-D nano-PANI are proposed based on the complexity of the synthetic process, its characters, and the aspects of waste production and treatment in particular. In addition, potential solutions to these important issues are also proposed.
一维聚苯胺纳米材料(1-D纳米PANI)在超级电容器、传感器与致动器、电致变色器件、防腐涂层及其他纳米器件中具有广阔的应用前景。因此,需要迅速开发大规模商业化生产1-D纳米PANI的方法,以确保这种材料的广泛应用。到目前为止,已有报道称包括硬模板法、软模板法、界面聚合、快速混合聚合、稀溶液聚合和电化学聚合等方法可用于制备这种材料。在此,基于合成过程的复杂性、其特性,特别是废物产生与处理等方面,提出了一些与1-D纳米PANI商业化生产相关的重要问题。此外,还提出了针对这些重要问题的潜在解决方案。