Cho Sunghun, Lee Jun Seop, Joo Hyeonseo
School of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Korea.
Department of Materials Science and Engineering, College of Engineering, Gachon University, Seongnam 13120, Korea.
Polymers (Basel). 2019 Nov 29;11(12):1965. doi: 10.3390/polym11121965.
Solution-processable conducting polymers (CPs) are an effective means for producing thin-film electrodes with tunable thickness, and excellent electrical, electrochemical, and optical properties. Especially, solution-processable polyaniline (PANI) composites have drawn a great deal of interest due to of their ease of film-forming, high conductivity up to 10 S/cm, excellent redox behaviors, processability, and scalability. In this review, basic principles, fabrication methods, and applications of solution-processable PANI composites will be discussed. In addition, recent researches on the PANI-based electrodes for solar cells (SCs), electrochromic (EC) windows, thermoelectric (TE) materials, supercapacitors, sensors, antennas, electromagnetic interference (EMI) shielding, organic field-effect transistors (OFETs), and anti-corrosion coatings will be discussed. The presented examples in this review will offer new insights in the design and fabrication of high-performance electrodes from the PANI composite solutions for the development of thin-film electrodes for state-of-art applications.
可溶液加工的导电聚合物（CPs）是制备具有可调厚度且具备优异电学、电化学和光学性能的薄膜电极的有效手段。特别是，可溶液加工的聚苯胺（PANI）复合材料因其易于成膜、高达10 S/cm的高电导率、优异的氧化还原行为、可加工性和可扩展性而备受关注。在本综述中，将讨论可溶液加工的PANI复合材料的基本原理、制备方法及应用。此外，还将讨论基于PANI的电极在太阳能电池（SCs）、电致变色（EC）窗、热电（TE）材料、超级电容器、传感器、天线、电磁干扰（EMI）屏蔽、有机场效应晶体管（OFETs）及防腐涂层方面的最新研究。本综述中给出的实例将为从PANI复合溶液设计和制备高性能电极以开发用于先进应用的薄膜电极提供新的见解。
