Nanosheets of tungsten disulfide (WS) were used to improve the physicochemical properties of reduced graphene oxide aerogel (rGA). The nanosheets were directly integrated into 3D hybrid architecture of rGA by a solvothermal mixing method by which the WS sheets were assembled onto the conductive graphene network. WS with highly exfoliated and defect-rich structure made the WS/rGA composite possess plentiful active sites, and this enhanced the electrocatalytic capability of the composite. The introduction of poorly conductive WS into 3D rGA system decreases the background current of rGA when used as electrode material. This is advantageous in terms of signal to-noise ratio and analytical performance in general. The WS/rGA electrode, best operated at a potential of 0.68 V (vs. SCE) has a linear response in the 0.01 to 130 μM nitrite concentration range with a low detection limit of 3 nM (at S/N = 3). It is selective, reproducible, stable and is successfully applied to the determination of nitrite in spiked bacon samples. Graphical Abstract Schematic presentation of an electrochemically modified electrode for the detection of nitrite based on 3D tungsten disulfide/reduced graphene oxide aerogel (WS/rGA).