Wu Haishan, Zhang Weiwei, Wu Junjie, Chi Yuwu
MOE Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, and College of Chemistry , Fuzhou University , Fuzhou , Fujian 350108 , China.
ACS Appl Mater Interfaces. 2019 May 8;11(18):16713-16719. doi: 10.1021/acsami.9b02495. Epub 2019 Apr 29.
Nowadays, people are facing more and more threats from solar UV radiation due to global ozone layer depletion and the ozone hole. Therefore, it is highly desirable to develop a fast, simple, and sensitive sensor for solar UV radiation. In this work, recently emerging perovskite quantum dots (PQDs) with excellent optical properties are used for sensing solar UV radiation. PQDs with high quantum yields are protected in solid paraffin to obtain paraffin-PQD composite (P-PQD) film. The hydrophobic and compact paraffin not only can protect PQDs from degradation by water and air for long-term use but also is transparent to UV light and thus maintains the high quantum yield of PQDs. The P-PQD film shows high sensing sensitivity for solar UV radiation based on which a novel visual ratiometric luminescence sensing strategy for UV light has been developed. The visual ratiometric luminescence sensor for solar UV radiation adopts a paraffin-encapsulated red fluorescence PQD (P-r-PQD) film as the sensing unit for UV light and a green luminescence light-emitting diode as reference light. When exposed to different solar UV radiation, the sensing film shows wide color variations from green to red, which can easily observed by the naked eye or recorded by a camera. On the basis of this, a simple and visualized solar UV index-reporting system has been established.
如今,由于全球臭氧层损耗和臭氧空洞,人们正面临来自太阳紫外线辐射的越来越多的威胁。因此,开发一种用于太阳紫外线辐射的快速、简单且灵敏的传感器是非常有必要的。在这项工作中,具有优异光学性质的最近新兴的钙钛矿量子点(PQDs)被用于传感太阳紫外线辐射。具有高量子产率的PQDs被保护在固体石蜡中以获得石蜡-PQD复合材料(P-PQD)薄膜。疏水且致密的石蜡不仅可以保护PQDs免受水和空气的降解以便长期使用,而且对紫外线是透明的,从而保持PQDs的高量子产率。P-PQD薄膜对太阳紫外线辐射表现出高传感灵敏度,基于此开发了一种用于紫外线的新型可视化比率发光传感策略。用于太阳紫外线辐射的可视化比率发光传感器采用石蜡封装的红色荧光PQD(P-r-PQD)薄膜作为紫外线的传感单元以及绿色发光二极管作为参考光。当暴露于不同的太阳紫外线辐射时,传感薄膜显示出从绿色到红色的广泛颜色变化,这可以通过肉眼轻松观察到或由相机记录下来。基于此,建立了一个简单且可视化的太阳紫外线指数报告系统。