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基于明胶的纳米复合材料的制备及表征,其中包含壳聚糖纳米纤维和 ZnO 纳米粒子。

Preparation and characterization of gelatin-based nanocomposite containing chitosan nanofiber and ZnO nanoparticles.

机构信息

Department of Food Science and Technology, Faculty of Agriculture, Urmia University, Urmia, Iran; Department of Food Science and Technology, Tabriz Branch, Islamic Azad University, Tabriz, Iran.

Department of Food Science and Technology, Tabriz Branch, Islamic Azad University, Tabriz, Iran.

出版信息

Carbohydr Polym. 2019 Jul 15;216:376-384. doi: 10.1016/j.carbpol.2019.03.062. Epub 2019 Apr 4.

Abstract

There is an increasing interest toward biodegradable active packaging because of consumer demand and environmental concerns. Despite this interest, poor thermal, mechanical, and water barrier properties of biodegradable polymers such as gelatin limit their application in food packaging. In this study, to prevail these limitations, the gelatin-based nanocomposite containing chitosan nanofiber (CHNF) and ZnO nanoparticles (ZnONPs) were fabricated and characterized by FTIR, SEM, and DSC analyses. The results showed the appropriate interactions between gelatin matrix, CHNF and ZnONPs due to their good compatibility. Additionally, the nanocomposite showed high mechanical and water barrier properties due to its high dense and less permeable structure. The incorporation of CHNF compensated the negative effect of ZnONPs on the color properties of gelatin film. In addition, the synergistic effect between CHNF and ZnONPs improved the antibacterial activity of nanocomposite. In conclusion, the fabricated bio nanocomposite indicated considerable potential for food packaging.

摘要

由于消费者的需求和对环境的关注,可生物降解的活性包装越来越受到关注。尽管如此,明胶等可生物降解聚合物的热学、力学和水阻隔性能较差,限制了它们在食品包装中的应用。在这项研究中,为了克服这些限制,制备了含有壳聚糖纳米纤维(CHNF)和氧化锌纳米粒子(ZnONPs)的基于明胶的纳米复合材料,并通过傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)和差示扫描量热法(DSC)进行了分析。结果表明,由于其良好的相容性,明胶基体、CHNF 和 ZnONPs 之间存在适当的相互作用。此外,由于其高密度和低渗透性结构,纳米复合材料表现出高的力学和水阻隔性能。CHNF 的加入弥补了 ZnONPs 对明胶膜颜色性能的负面影响。此外,CHNF 和 ZnONPs 之间的协同效应提高了纳米复合材料的抗菌活性。总之,所制备的生物纳米复合材料表明其在食品包装方面具有相当大的潜力。

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