Zinser Caroline M, Nahra Fady, Falivene Laura, Brill Marcel, Cordes David B, Slawin Alexandra M Z, Cavallo Luigi, Cazin Catherine S J, Nolan Steven P
EaStCHEM School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, UK.
Chem Commun (Camb). 2019 Jun 6;55(47):6799-6802. doi: 10.1039/c9cc03171e.
A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.
已合成了一类新型的[Au(NHC)(Bpin)]配合物，并使用计算和实验方法研究了它们不同寻常的反应活性。金硼基配合物表现出意想不到的高稳定性和反应活性。
