Istanbul University-Cerrahpaşa, Engineering Faculty, Department of Chemical Engineering, 34320, Avcılar, Istanbul, Turkey.
J Pharm Biomed Anal. 2019 Sep 10;174:324-329. doi: 10.1016/j.jpba.2019.05.059. Epub 2019 May 27.
One of the main issues of Green Chemistry, encouraging innovative technologies, where incorporates solutions to reduce or eliminate existing pollution problems, is the development of novel green solvents. Therefore, design of environmentally friendly solvents has had a strategic preface in the framework of green technologies recently. When looking at the last 20 years, it is seen that Ionic Liquids (IL) has attracted attention as new generation green design solvents. However, IL has disadvantages such as toxicity, poor biological degradability and high cost, except for the green-labelled properties of solvents (volatile, non-flammable and reusability). Hence, efforts have been made to develop extremely inexpensive solvents at a minimal level of harm to the environment in addition to the present attractive properties of IL. Deep Eutectic Liquid (DEL), which has been lately introduced concept in the literature, is a novel tailor-made solvent. Furthermore, the relevant liquids exhibit physicochemical properties similar to those of conventional ionic liquids, but DELs are much cheaper and environmentally friendly. Due to its advantages, there is a growing interest in many of the research areas such as catalysis, organic synthesis, extraction processes, electrochemistry and material chemistry.
绿色化学的主要问题之一是鼓励创新技术,其中包括解决现有污染问题的解决方案,这就是新型绿色溶剂的开发。因此,在绿色技术的框架下,环保溶剂的设计最近具有战略意义。回顾过去 20 年,可以看出离子液体(IL)作为新一代绿色设计溶剂引起了人们的关注。然而,IL 除了具有溶剂的绿色标签特性(挥发性、不可燃性和可重复使用性)外,还存在毒性、生物降解性差和成本高的缺点。因此,除了 IL 的现有吸引力之外,人们还努力开发极其廉价且对环境危害最小的溶剂。深共晶溶剂(DEL)是最近在文献中提出的新概念,是一种新型定制溶剂。此外,相关液体表现出与常规离子液体相似的物理化学性质,但 DEL 便宜得多,对环境也更友好。由于其优势,它在许多研究领域(如催化、有机合成、萃取过程、电化学和材料化学)引起了越来越多的兴趣。
J Pharm Biomed Anal. 2019-5-27
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