生物催化氧化还原过程采用绿色反应介质。
Biocatalyzed Redox Processes Employing Green Reaction Media.
机构信息
Institute of Natural Resources and Agrobiology of Seville (IRNAS), CSIC, 41012 Seville, Spain.
Organic Chemistry Department, University of Seville, 41012 Seville, Spain.
出版信息
Molecules. 2020 Jul 1;25(13):3016. doi: 10.3390/molecules25133016.
The application of biocatalysts to perform reductive/oxidative chemical processes has attracted great interest in recent years, due to their environmentally friendly conditions combined with high selectivities. In some circumstances, the aqueous buffer medium normally employed in biocatalytic procedures is not the best option to develop these processes, due to solubility and/or inhibition issues, requiring biocatalyzed redox procedures to circumvent these drawbacks, by developing novel non-conventional media, including the use of biobased solvents, reactions conducted in neat conditions and the application of neoteric solvents such as deep eutectic solvents.
近年来，由于生物催化剂具有环保条件和高选择性，因此将其应用于进行还原/氧化化学过程引起了极大的关注。在某些情况下，由于溶解度和/或抑制问题，生物催化过程中通常使用的水缓冲介质不是开发这些过程的最佳选择，这就需要通过开发新型非常规介质（包括使用生物基溶剂、在纯反应条件下进行反应以及应用新型溶剂如深共晶溶剂）来规避这些缺点，从而实现生物催化氧化还原过程。
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