Wei Longfu, Zhang Junxian, Deng Weiping, Xie Shunji, Zhang Qinghong, Wang Ye
State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Chem Commun (Camb). 2019 Jul 4;55(55):8013-8016. doi: 10.1039/c9cc02877c.
The conversion of biomass-derived molecules into adipic acid represents a highly attractive green route for sustainable production of adipic acid, a key monomer of nylon 66 and polyurethane. Here, we report the direct synthesis of adipic acid from 2,5-furandicarboxylic acid, which can be obtained from cellulose-based 5-hydroxymethylfurfural, using a niobic acid-supported platinum catalyst under hydrogen in water.
将生物质衍生分子转化为己二酸是一种极具吸引力的绿色途径，可实现尼龙66和聚氨酯的关键单体己二酸的可持续生产。在此，我们报道了以纤维素基5-羟甲基糠醛制得的2,5-呋喃二甲酸为原料，在水中氢气氛围下，使用铌酸负载的铂催化剂直接合成己二酸的方法。
