Department of Chemistry and Biochemistry, Biomolecular Sciences Programme, Laurentian University, Sudbury, Ontario, Canada.
Department of Organic Chemistry, Faculty of Chemistry and Technology, University of Split, Split, Croatia.
Nat Prod Res. 2021 Feb;35(3):494-498. doi: 10.1080/14786419.2019.1633643. Epub 2019 Jun 27.
The glucosinolate (GSL) profiles (inflorescence, stem, root, and fruit) of the wild-growing plant L. (Brassicaceae) from Croatia was established by LC-MS analysis. During this investigation, we confirmed the presence of benzyl- (), 3-methoxybenzyl- (), 4-hydroxybenzyl- (), 4-methoxyindol-3-ylmethyl- () GSLs and reported for the first time in the plant the presence of (2 )-hydroxybut-3-enyl- (), (2)-hydroxybut-3-enyl- (), but-3-enyl- (), and 2-phenylethyl- () GSLs. Finally, 3-hydroxybenzyl GSL () was isolated for the first time from inflorescence and characterised by spectroscopic data interpretation.
采用 LC-MS 分析方法建立了来自克罗地亚的野生 L.（十字花科）的植物花、茎、根和果实中的硫代葡萄糖苷（GSL）图谱。在这项研究中，我们证实了存在苄基（）、3-甲氧基苄基（）、4-羟苄基（）、4-甲氧基吲哚-3-基甲基（）GSL，并首次在该植物中报告存在（2-）-羟基丁-3-烯基（）、（2-）-羟基丁-3-烯基（）、丁-3-烯基（）和 2-苯乙基（）GSL。最后，首次从花中分离出 3-羟基苄基 GSL（），并通过光谱数据解释对其进行了表征。
