一种卤键催化的纳扎罗夫环化反应。
A halogen-bonding-catalysed Nazarov cyclisation reaction.
作者信息
Dreger Alexander, Wonner Patrick, Engelage Elric, Walter Sebastian M, Stoll Raphael, Huber Stefan M
机构信息
Department of Chemistry and Biochemistry, Ruhr-Universität Bochum, Universitätsstraße 150, 44801 Bochum, Germany.
出版信息
Chem Commun (Camb). 2019 Jul 11;55(57):8262-8265. doi: 10.1039/c9cc02816a.
PMID:31243400
Abstract
Various neutral, mono- and dicationic halogen bond donors were screened for their ability to act as catalysts in a Nazarov cyclisation reaction. Using a highly preorganized dicationic catalyst with a noncoordinating counterion proved essential for high activity.
摘要
筛选了各种中性、单阳离子和双阳离子卤素键供体，以考察它们在纳扎罗夫环化反应中作为催化剂的能力。事实证明，使用具有非配位抗衡离子的高度预组织双阳离子催化剂对于高活性至关重要。
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