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低温剥离法制备六方氮化硼纳米片。

Facile Production of Hexagonal Boron Nitride Nanoparticles by Cryogenic Exfoliation.

机构信息

School of Mathematical and Physical Sciences , University of Technology Sydney , Ultimo , NSW 2007 , Australia.

Laboratory of Nanoscale Biology, Institute of Bioengineering, School of Engineering , École Polytechnique Fédérale de Lausanne (EPFL) , 1015 Lausanne , Switzerland.

出版信息

Nano Lett. 2019 Aug 14;19(8):5417-5422. doi: 10.1021/acs.nanolett.9b01913. Epub 2019 Jul 9.

Abstract

Fluorescent nanoparticles with optically robust luminescence are imperative to applications in imaging and labeling. Here we demonstrate that hexagonal boron nitride (hBN) nanoparticles can be reliably produced using a scalable cryogenic exfoliation technique with sizes below 10 nm. The particles exhibit bright fluorescence generated by color centers that act as atomic-size quantum emitters. We analyze their optical properties, including emission wavelength, photon-statistics, and photodynamics, and show that they are suitable for far-field super-resolution fluorescence nanoscopy. Our results provide a foundation for exploration of hBN nanoparticles as candidates for bioimaging, labeling, as well as biomarkers that are suitable for quantum sensing.

摘要

具有光学稳健发光的荧光纳米粒子对于成像和标记应用至关重要。在这里,我们证明了使用可扩展的低温剥落技术可以可靠地生产尺寸小于 10nm 的六方氮化硼 (hBN) 纳米粒子。这些颗粒表现出由色心产生的明亮荧光,色心充当原子尺寸的量子发射器。我们分析了它们的光学性质,包括发射波长、光子统计和光动力学,并表明它们适用于远场超分辨率荧光纳米显微镜。我们的结果为探索 hBN 纳米粒子作为生物成像、标记以及适合量子传感的生物标志物的候选物提供了基础。

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