Festa Alexey A, Voskressensky Leonid G, Van der Eycken Erik V
Peoples' Friendship University of Russia (RUDN University), Miklukho-Maklaya st. 6, Moscow, 117198, Russian Federation.
Chem Soc Rev. 2019 Aug 12;48(16):4401-4423. doi: 10.1039/c8cs00790j.
The use of visible light and photoredox catalysis emerged as a powerful and sustainable tool for organic synthesis, showing the high value of distinctly different ways of bond creation. Indoles and related heterocycles are widely-present in natural products, biologically active compounds, drugs, and agrochemicals. This review summarises the impact of visible light-promoted chemistry on the functionalization of indoles and on the synthesis and modification of indolines, indolin-2-ones, indolin-3-ones, and isatins. Almost 100 references starting from 2012 are cited.
可见光和光氧化还原催化的应用已成为有机合成中一种强大且可持续的工具，展现出不同键生成方式的高价值。吲哚及相关杂环广泛存在于天然产物、生物活性化合物、药物和农用化学品中。本综述总结了可见光促进的化学对吲哚官能化以及对二氢吲哚、吲哚 - 2 - 酮、吲哚 - 3 - 酮和异吲哚酮的合成与修饰的影响。引用了从2012年起的近100篇参考文献。
