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直接纺丝和致密化方法制备高性能碳纳米管纤维。

Direct spinning and densification method for high-performance carbon nanotube fibers.

机构信息

Institute of Advanced Composite Materials, Korea Institute of Science and Technology (KIST), 92 Chudong-Ro, Bongdong-Eup, Wanju-Gun, Jeonbuk, 55324, South Korea.

Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-Ro, Yuseong-Gu, Daejeon, 34141, South Korea.

出版信息

Nat Commun. 2019 Jul 4;10(1):2962. doi: 10.1038/s41467-019-10998-0.

Abstract

Developing methods to assemble nanomaterials into macroscopic scaffolds is of critical significance at the current stage of nanotechnology. However, the complications of the fabrication methods impede the widespread usages of newly developed materials even with the superior properties in many cases. Here, we demonstrate the feasibility of a highly-efficient and potentially-continuous fiber-spinning method to produce high-performance carbon nanotube (CNT) fiber (CNTF). The processing time is <1 min from synthesis of CNTs to fabrication of highly densified and aligned CNTFs. CNTFs that are fabricated by the developed spinning method are ultra-lightweight, strong (specific tensile strength = 4.08 ± 0.25 Ntex), stiff (specific tensile modulus = 187.5 ± 7.4 Ntex), electrically conductive (2,270 S mkg), and highly flexible (knot efficiency = 48 ± 15%), so they are suitable for various high-value fabric-based applications.

摘要

在当前的纳米技术阶段,将纳米材料组装成宏观支架的方法的开发具有重要意义。然而,制造方法的复杂性阻碍了新型材料的广泛应用,即使在许多情况下它们具有优越的性能也是如此。在这里,我们展示了一种高效且具有潜在连续性的纤维纺丝方法来生产高性能碳纳米管(CNT)纤维(CNTF)的可行性。从 CNT 的合成到高度致密和对齐的 CNTF 的制造,加工时间<1 分钟。通过开发的纺丝方法制造的 CNTF 超轻、强(比拉伸强度=4.08±0.25Ntex)、硬(比拉伸模量=187.5±7.4Ntex)、导电(2270Smkg)和高柔韧性(结效率=48±15%),因此它们适用于各种基于高价值织物的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd3c/6609687/aef7ab8723df/41467_2019_10998_Fig1_HTML.jpg

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