The School of Biological and Chemical Sciences, Queen Mary University of London, Mile End Road, London, E1 4NS, UK.
Org Biomol Chem. 2019 Jul 24;17(29):6985-6988. doi: 10.1039/c9ob00745h.
We report an investigation towards a unified total synthesis of the Korean sponge derived sesterterpenoids, phorones A (1) and B (2), via a biomimetic strategy. This work has established a new synthetic strategy to the parent ansellane sesterterpenoid skeleton with unanticipated diversion to a biogenetically related pathway.
我们报告了一项针对韩国海绵源甾体倍半萜 phorones A（1）和 B（2）的统一全合成的研究，采用了仿生策略。这项工作建立了一个新的合成策略，用于母体 ansellane 甾体倍半萜骨架，具有意想不到的生物相关途径的转变。
