Kosmaca Jelena, Meija Raimonds, Antsov Mikk, Kunakova Gunta, Sondors Raitis, Iatsunskyi Igor, Coy Emerson, Doherty Jessica, Biswas Subhajit, Holmes Justin D, Erts Donats
Institute of Chemical Physics, University of Latvia, 1 Jelgavas str., Riga, LV-1004, Latvia.
NanoBioMedical Centre, Adam Mickiewicz University, Wszechnicy Piastowskiej str. 3, 61-614, Poznan, Poland.
Nanoscale. 2019 Jul 28;11(28):13612-13619. doi: 10.1039/c9nr02740h. Epub 2019 Jul 10.
Germanium tin (GeSn) has been proposed as a promising material for electronic and optical applications due to the formation of a direct band-gap at a Sn content >7 at%. Furthermore, the ability to manipulate the properties of GeSn at the nanoscale will further permit the realisation of advanced mechanical devices. Here we report for the first time the mechanical properties of GeSn nanowires (7.1-9.7 at% Sn) and assess their suitability as nanoelectromechanical (NEM) switches. Electron microscopy analysis showed the nanowires to be single crystalline, with surfaces covered by a thin native amorphous oxide layer. Mechanical resonance and bending tests at different boundary conditions were used to obtain size-dependent Young's moduli and to relate the mechanical characteristics of the alloy nanowires to geometry and Sn incorporation. The mechanical properties of the GeSn nanowires make them highly promising for applications in next generation NEM devices.
锗锡(GeSn)由于在锡含量大于7原子百分比时形成直接带隙,已被提议作为一种用于电子和光学应用的有前景的材料。此外,在纳米尺度上操纵GeSn特性的能力将进一步推动先进机械设备的实现。在此,我们首次报道了锗锡纳米线(锡含量为7.1 - 9.7原子百分比)的机械性能,并评估了它们作为纳米机电(NEM)开关的适用性。电子显微镜分析表明,纳米线为单晶结构,其表面覆盖着一层薄的天然非晶氧化物层。通过在不同边界条件下进行机械共振和弯曲测试,获得了与尺寸相关的杨氏模量,并将合金纳米线的机械特性与几何形状和锡掺入量联系起来。锗锡纳米线的机械性能使其在下一代纳米机电设备应用中极具前景。