Gregory Philip D, Frye Matthew D, Blackmore Jacob A, Bridge Elizabeth M, Sawant Rahul, Hutson Jeremy M, Cornish Simon L
Joint Quantum Centre (JQC), Durham-Newcastle, Department of Physics, Durham University, Durham, DH1 3LE, UK.
Joint Quantum Centre (JQC), Durham-Newcastle, Department of Chemistry, Durham University, Durham, DH1 3LE, UK.
Nat Commun. 2019 Jul 15;10(1):3104. doi: 10.1038/s41467-019-11033-y.
Understanding and controlling collisions is crucial to the burgeoning field of ultracold molecules. All experiments so far have observed fast loss of molecules from the trap. However, the dominant mechanism for collisional loss is not well understood when there are no allowed 2-body loss processes. Here we experimentally investigate collisional losses of nonreactive ultracold RbCs molecules, and compare our findings with the sticky collision hypothesis that pairs of molecules form long-lived collision complexes. We demonstrate that loss of molecules occupying their rotational and hyperfine ground state is best described by second-order rate equations, consistent with the expectation for complex-mediated collisions, but that the rate is lower than the limit of universal loss. The loss is insensitive to magnetic field but increases for excited rotational states. We demonstrate that dipolar effects lead to significantly faster loss for an incoherent mixture of rotational states.
理解和控制碰撞对于超冷分子这个新兴领域至关重要。迄今为止,所有实验都观察到分子从陷阱中快速损失。然而,当不存在允许的双体损失过程时,碰撞损失的主导机制尚不清楚。在此,我们通过实验研究了非反应性超冷铷铯分子的碰撞损失,并将我们的发现与粘性碰撞假说进行了比较,该假说认为分子对会形成长寿命的碰撞复合物。我们证明,占据其转动和超精细基态的分子损失最好用二阶速率方程来描述,这与对复合物介导碰撞的预期一致,但速率低于普遍损失的极限。这种损失对磁场不敏感,但对于激发的转动状态会增加。我们证明,偶极效应会导致转动状态的非相干混合物的损失明显更快。