Institute for Molecules and Materials, Radboud University, Heijendaalseweg 135, 6525 AJ Nijmegen, The Netherlands.
J Phys Chem A. 2023 Mar 9;127(9):2194-2211. doi: 10.1021/acs.jpca.3c00797. Epub 2023 Feb 24.
Scattering resonances due to the dipole-dipole interaction between ultracold molecules, induced by static or microwave fields, are studied theoretically. We develop a method for coupled-channel calculations that can efficiently impose many short-range boundary conditions, defined by a short-range phase shift and loss probability as in quantum defect theory. We study how resonances appear as the short-range loss probability is lowered below the universal unit probability. This may become realizable for nonreactive ultracold molecules in blue-detuned box potentials.
由于超冷分子之间的偶极-偶极相互作用而产生的散射共振,通过静态或微波场来诱导,在理论上进行了研究。我们开发了一种用于耦合通道计算的方法,该方法可以有效地施加许多短程边界条件,这些边界条件由短程相移和损耗概率定义,如量子亏损理论中所述。我们研究了在短程损耗概率降低到低于普遍单位概率时,共振如何出现。对于在蓝失谐盒势中的非反应性超冷分子,这可能是可行的。