Dark-field spectroscopy: development, applications and perspectives in single nanoparticle catalysis.

Dark-field microscopy (DFM) is an effective method to detect the scattering signal from single nanoparticles. This technique could break through the 200 nm limit resolution of ordinary optical microscopes. It even can observe the submicron particles of 20-200 nm. Moreover, from 2000, DFM was coupled with a spectrometer to measure the scattering spectra of single silver nanoparticles. Then, dark-field spectroscopy becomes a very important plasmon spectroscopy technique for single nanoparticles. Usually, plasmonic nanoparticles are the major research target, because they have unique optical properties due to their localized surface plasmon resonance (LSPR), which can be influenced by many factors, such as composition, size, morphology, the refractive index of the surrounding medium etc. When surface chemical reactions occur on a single nanoparticle, it could induce the variation of these factors. Then, the structure-activity relationship for these nanoparticle catalysts can be studied at a single nanoparticle level and in real time. This review mainly summarized the development of dark-field spectroscopy, spectrometers, light sources, and other accessories, which greatly improved the imaging capabilities of dark-field spectroscopy. Meanwhile, the applications of dark-field spectroscopy in single-particle catalysis such as chemocatalysis, photocatalysis, electrocatalysis and biocatalysis are also reviewed.