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采用可见高光谱成像技术对彩色玻璃窗中的色素进行原位分析。

Analysis of chromophores in stained-glass windows using Visible Hyperspectral Imaging in-situ.

机构信息

Unidade de investigação VICARTE-Vidro e Cerâmica para as Artes, Campus de Caparica, FCT-UNL, Quinta da Torre, 2829-516 Caparica, Portugal; Instituto de Cerámica y Vidrio, Consejo Superior de Investigaciones Científicas (ICV-CSIC), c/Kelsen 5, Campus de Cantoblanco, 28049 Madrid, Spain.

SMAArt Centre, c/o Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di Perugia, Via Elce di Sotto, 8, 06123 Perugia, Italy.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2019 Dec 5;223:117378. doi: 10.1016/j.saa.2019.117378. Epub 2019 Jul 9.

Abstract

This work presents the implementation of Visible Hyperspectral Imaging for the in-situ analysis of glass chromophores in two glass windows from the Casa-Museu Dr. Anastácio Gonçalves (Lisbon, Portugal). The measurements were taken inside the building using natural sunlight as the illumination source. In addition, advantages and disadvantages of the followed methodology are discussed. The Dining Room glass window presents glasses colored in bulk with iron, manganese, cobalt, copper, and chromium; silver staining was also detected and was used to create the yellow and orange colors. The Atelier panel was produced with uncolored glasses painted with grisaille and enamels; the chromophores identified are similar to the species identified in the Dining Room panel.

摘要

本工作展示了可见光谱成像技术在 Casa-Museu Dr. Anastácio Gonçalves(葡萄牙里斯本)两个玻璃窗体内玻璃着色剂原位分析中的应用。测量是在建筑物内使用自然光作为照明光源进行的。此外,还讨论了所采用方法的优缺点。餐厅玻璃窗采用铁、锰、钴、铜和铬整体着色的玻璃;还检测到银染色,用于产生黄色和橙色。工作室嵌板由未着色的玻璃制成,并用灰度和珐琅彩绘;鉴定出的生色团与餐厅嵌板中鉴定出的物种相似。

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