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用于智能织物的半液态金属增强型高导电性可穿戴电子产品。

Semiliquid Metal Enabled Highly Conductive Wearable Electronics for Smart Fabrics.

作者信息

Guo Rui, Wang Huimin, Sun Xuyang, Yao Siyuan, Chang Hao, Wang Hongzhang, Liu Jing, Zhang Yingying

机构信息

Department of Biomedical Engineering, School of Medicine , Tsinghua University , Beijing 100084 , PR China.

Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education, Department of Chemistry , Tsinghua University , Beijing 100084 , PR China.

出版信息

ACS Appl Mater Interfaces. 2019 Aug 21;11(33):30019-30027. doi: 10.1021/acsami.9b08067. Epub 2019 Aug 7.

Abstract

Wearable electronics incorporating electronic components into commonly used fabrics can serve as new-generation personalized health-care systems for applications ranging from health-care monitoring to disease treatment. Conventional rigid materials including gold, silver, and copper generally require a complicated fabrication process to be sewn into clothes. At the same time, other high-stretchable nonmetal materials such as conductive polymers generally have a limitation of low electroconductivity, restricting their further applications. Recently, gallium-based liquid metals have exhibited superior advantages in flexible electronics and have presented valuable potential in creative printing technologies. Here, we proposed a novel wearable electronics prepared through roller printing technology based on the adhesion difference of semiliquid metal (Cu-EGaIn, eutectic gallium-indium mixed with copper microparticles) on cotton fabrics and polyvinyl acetate (PVAC) glue. Results have shown that the surface topography and chemical interaction of fabrics and PVAC glue determine the adhesion effect with the Cu-EGaIn mixture. The electric experiments have demonstrated the electromechanical stability of the fabricated lines on fabrics. Further, a series of smart fabrics were developed including an interactive circuit, stretchable light-emitting diode array, and thermal management device with advantages of easy operation, low cost, and large-area fabrication to show practical applications in the method. This strategy may play an important role in the design and fabrication of smart fabrics, contributing to the development of customized health-care systems.

摘要

将电子元件集成到常用织物中的可穿戴电子产品可作为新一代个性化医疗保健系统,用于从医疗保健监测到疾病治疗等各种应用。包括金、银和铜在内的传统刚性材料通常需要复杂的制造工艺才能缝入衣服中。同时,其他高拉伸性的非金属材料,如导电聚合物,通常存在导电性低的局限性,限制了它们的进一步应用。最近,镓基液态金属在柔性电子领域展现出卓越优势,并在创新印刷技术中呈现出宝贵潜力。在此,我们基于半液态金属(Cu-EGaIn,即共晶镓铟与铜微粒混合)在棉织物和聚醋酸乙烯酯(PVAC)胶水之间的附着力差异,通过辊印技术提出了一种新型可穿戴电子产品。结果表明,织物与PVAC胶水的表面形貌和化学相互作用决定了与Cu-EGaIn混合物的附着效果。电学实验证明了在织物上制作的线路具有机电稳定性。此外,还开发了一系列智能织物,包括交互式电路、可拉伸发光二极管阵列和热管理装置,这些织物具有操作简便、成本低和可大面积制作的优点,展示了该方法的实际应用。这种策略可能在智能织物的设计和制造中发挥重要作用,有助于定制医疗保健系统的发展。

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