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热循环后多次表面处理提高二硅酸锂陶瓷与树脂水门汀的粘结强度。

Enhanced bonding strength between lithium disilicate ceramics and resin cement by multiple surface treatments after thermal cycling.

机构信息

Department of Prosthodontics, Stomatological Hospital, Tianjin Medical University, Tianjin, China.

School of Materials Science and Engineering, Tianjin University, Tianjin, China.

出版信息

PLoS One. 2019 Jul 25;14(7):e0220466. doi: 10.1371/journal.pone.0220466. eCollection 2019.

Abstract

All-ceramic restoration has become a popular technology for dental restoration; however, the relative bond strength between the ceramic and resin limits its further application. Long-term high bond strength, especially after thermal cycling, is of great importance for effective restoration. The effect of physical and/or chemical surface treatments on bonding durability is seldom reported. To overcome this problem, we investigate the bond strength between lithium disilicate ceramics (LDC) and two kinds of resin cements before and after thermal cycling for a variety of surface treatments including hydrofluoric acid, two kinds of silane and a combined effect. The shear bond strength in every group is characterized by universal mechanical testing machine averaged by sixteen-time measurements. The results show that when treated with HF and a mixed silane, the LDC surface shows maximum bonding strengths of 27.1 MPa and 23.3 MPa with two different resin cements after 5000 thermal cycling, respectively, indicating an excellent ability to resist the damage induced by cyclic expansion and contraction. This long-term high bond strength is attributed to the combined effect of micromechanical interlocking (physical bonding) and the formation of Si-O-Si and -C-C- at the interface (chemical bonding). This result offers great potential for enhancing bond strength for all-ceramic restoration by optimizing the surface treatment.

摘要

全瓷修复已成为一种流行的牙科修复技术;然而,陶瓷和树脂之间的相对结合强度限制了其进一步的应用。长期的高结合强度,特别是在热循环之后,对于有效的修复非常重要。物理和/或化学表面处理对结合耐久性的影响很少有报道。为了克服这个问题,我们研究了锂硅酸钠陶瓷(LDC)与两种树脂水门汀在热循环前后的结合强度,对各种表面处理方法进行了研究,包括氢氟酸、两种硅烷和联合处理。通过对十六次测量的平均值,用万能材料试验机对每组的剪切结合强度进行了特征描述。结果表明,经 HF 和混合硅烷处理后,LDC 表面在经过 5000 次热循环后,与两种不同的树脂水门汀的结合强度分别达到 27.1 MPa 和 23.3 MPa,显示出优异的抵抗循环膨胀和收缩引起的损伤的能力。这种长期的高强度结合归因于微机械联锁(物理结合)和界面处 Si-O-Si 和 -C-C-形成(化学结合)的共同作用。该结果为优化表面处理以提高全瓷修复的结合强度提供了巨大的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4748/6657896/69d37b5079c5/pone.0220466.g001.jpg

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