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使用氧化铁纳米材料无溶剂制备1,8-二氧代八氢呫吨

Solvent-Free Preparation of 1,8-Dioxo-Octahydroxanthenes Employing Iron Oxide Nanomaterials.

作者信息

Rajabi Fatemeh, Abdollahi Mohammad, Diarjani Elham Sadat, Osmolowsky Mikhail G, Osmolovskaya Olga M, Gómez-López Paulette, Puente-Santiago Alain R, Luque Rafael

机构信息

Department of Science, Payame Noor University, Tehran 19569, Iran.

Department of Chemistry, University of Guilan, Rasht 1914, Iran.

出版信息

Materials (Basel). 2019 Jul 26;12(15):2386. doi: 10.3390/ma12152386.

DOI:10.3390/ma12152386
PMID:31357446
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6695819/
Abstract

In this study, 1,8-dioxo-octahydroxanthenes were prepared employing a simple, effective and environmentally sound approach utilizing an iron oxide nanocatalyst under solventless conditions. The proposed iron oxide nanomaterial exhibited high product yields, short reaction times and a facile work-up procedure. The synthesized catalyst was also found to be highly stable and reusable under the investigated conditions (up to twelve consecutive cycles) without any significant loss in its catalytic activity.

摘要

在本研究中,采用一种简单、有效且环保的方法,在无溶剂条件下利用氧化铁纳米催化剂制备了1,8 - 二氧代 - 八氢呫吨。所提出的氧化铁纳米材料具有高产物产率、短反应时间和简便的后处理程序。还发现合成的催化剂在研究条件下(多达十二个连续循环)具有高度稳定性和可重复使用性,其催化活性没有任何显著损失。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a93c/6695819/eb7e52bbdc08/materials-12-02386-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a93c/6695819/4756624174ad/materials-12-02386-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a93c/6695819/243c492a98c6/materials-12-02386-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a93c/6695819/eb7e52bbdc08/materials-12-02386-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a93c/6695819/4756624174ad/materials-12-02386-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a93c/6695819/243c492a98c6/materials-12-02386-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a93c/6695819/eb7e52bbdc08/materials-12-02386-sch002.jpg

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