Reiterman Pavel, Holčapek Ondřej, Davidová Vendula, Jaskulski Roman, Keppert Martin
University Centre for Energy Efficient Buildings, Czech Technical University in Prague, Třinecká 1024, 273 43 Buštěhrad, Czech Republic.
Faculty of Civil Engineering, Czech Technical University in Prague, Thakurova 6, 166 29 Prague 6, Czech Republic.
Materials (Basel). 2019 Jul 29;12(15):2420. doi: 10.3390/ma12152420.
The growing utilization of various mineral additives in the building industry has caused concern worldwide to reduce the emissions of carbon dioxide from Portland cement (OPC) production. The present paper is focused on the determination of the degree of hydration of blended binding systems based on Portland cement. Blast furnace slag, fly ash, and ceramic powder are used in the study; they are applied by 12.5 wt.% up to 50% of OPC replacement. The evolution of the hydration process is monitored using thermogravimetry in selected time intervals to determine the degree of hydration; its ultimate value is obtained from numerical estimation using the Michaelis-Menten equation. However, due to the application of active mineral additives, the correction in terms of equivalent binder is conducted. Corrected values of the degree of hydration exhibit good fit with compressive strength.
建筑行业中各种矿物添加剂的使用日益增加,这引起了全球范围内对减少波特兰水泥(OPC)生产中二氧化碳排放的关注。本文重点在于测定基于波特兰水泥的混合粘结体系的水化程度。研究中使用了高炉矿渣、粉煤灰和陶瓷粉;它们的用量为OPC替代量的12.5重量%至50%。在选定的时间间隔内使用热重分析法监测水化过程的演变以确定水化程度;其最终值通过使用米氏方程的数值估算获得。然而,由于活性矿物添加剂的应用,进行了等效粘结剂方面的校正。水化程度的校正值与抗压强度显示出良好的拟合。