• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

采用液相外延法生长基于光活性卟啉的金属有机框架薄膜及其光电性能

The Growth of Photoactive Porphyrin-Based MOF Thin Films Using the Liquid-Phase Epitaxy Approach and their Optoelectronic Properties.

作者信息

Ngongang Ndjawa Guy Olivier, Tchalala Mohamed R, Shekhah Osama, Khan Jafar I, Mansour Ahmed E, Czaban-Jóźwiak Justyna, Weselinski Lukasz J, Ait Ahsaine Hassan, Amassian Aram, Eddaoudi Mohamed

机构信息

King Abdullah University of Science and Technology (KAUST), KAUST Solar Center (KSC), Physical Sciences and Engineering Division (PSE), Thuwal 23955-6900, Saudi Arabia.

Functional Materials Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center (AMPMC), Physical Science and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia.

出版信息

Materials (Basel). 2019 Aug 1;12(15):2457. doi: 10.3390/ma12152457.

DOI:10.3390/ma12152457
PMID:31375019
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6695608/
Abstract

This study reports on the optoelectronic properties of porphyrin-based metal-organic framework (MOF) thin films fabricated by a facile liquid-phase epitaxy approach. This approach affords the growth of MOF thin films that are free of morphological imperfections, more suitable for optoelectronic applications. Chemical modifications such as the porphyrin ligand metallation have been found to preserve the morphology of the grown films making this approach particularly suitable for molecular alteration of MOF thin film optoelectronic properties without compromising its mesoscale morphology significantly. Particularly, the metallation of the ligand was found to be effective to tune the MOF bandgap. These porphyrin-based MOF thin films were shown to function effectively as donor layers in solar cells based on a Fullerene-C acceptor. The ability to fabricate MOF solar cells free of a liquid-phase acceptor greatly simplifies device fabrication and enables pairing of MOFs as light absorbers with a wide range of acceptors including non-fullerene acceptors.

摘要

本研究报道了通过简便的液相外延方法制备的卟啉基金属有机框架（MOF）薄膜的光电性质。这种方法能够生长出无形态缺陷的MOF薄膜，更适合用于光电应用。已发现诸如卟啉配体金属化等化学修饰能够保持生长薄膜的形态，使得这种方法特别适用于在不显著损害其介观形态的情况下对MOF薄膜的光电性质进行分子改变。特别地，发现配体的金属化对于调节MOF的带隙是有效的。这些卟啉基MOF薄膜被证明在基于富勒烯-C受体的太阳能电池中作为供体层能有效发挥作用。制备不含液相受体的MOF太阳能电池的能力极大地简化了器件制造，并能够将作为光吸收剂的MOF与包括非富勒烯受体在内的多种受体配对。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/02febc598a75/materials-12-02457-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/118f45489d17/materials-12-02457-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/cf8035dd3260/materials-12-02457-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/c27cf5676da1/materials-12-02457-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/c2858266eeec/materials-12-02457-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/a881027ff0c2/materials-12-02457-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/e02c0c152dc8/materials-12-02457-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/dbf7e3279aef/materials-12-02457-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/3acd5378685f/materials-12-02457-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/3dfc91a78fc7/materials-12-02457-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/02febc598a75/materials-12-02457-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/118f45489d17/materials-12-02457-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/cf8035dd3260/materials-12-02457-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/c27cf5676da1/materials-12-02457-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/c2858266eeec/materials-12-02457-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/a881027ff0c2/materials-12-02457-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/e02c0c152dc8/materials-12-02457-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/dbf7e3279aef/materials-12-02457-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/3acd5378685f/materials-12-02457-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/3dfc91a78fc7/materials-12-02457-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d61/6695608/02febc598a75/materials-12-02457-g010.jpg

相似文献

1
The Growth of Photoactive Porphyrin-Based MOF Thin Films Using the Liquid-Phase Epitaxy Approach and their Optoelectronic Properties.采用液相外延法生长基于光活性卟啉的金属有机框架薄膜及其光电性能
Materials (Basel). 2019 Aug 1;12(15):2457. doi: 10.3390/ma12152457.
2
Photoconductivity in Metal-Organic Framework (MOF) Thin Films.金属有机框架（MOF）薄膜中的光电导性。
Angew Chem Int Ed Engl. 2019 Jul 8;58(28):9590-9595. doi: 10.1002/anie.201904475. Epub 2019 May 30.
3
Advanced Fabrication Method for the Preparation of MOF Thin Films: Liquid-Phase Epitaxy Approach Meets Spin Coating Method.用于 MOF 薄膜制备的先进制造方法：液相外延法与旋涂法的结合。
ACS Appl Mater Interfaces. 2016 Aug 10;8(31):20459-64. doi: 10.1021/acsami.6b04701. Epub 2016 Jul 27.
4
Efficient MOF-Sensitized Solar Cells Featuring Solvothermally Grown [100]-Oriented Pillared Porphyrin Framework-11 Films on ZnO/FTO Surfaces.在ZnO/FTO表面具有溶剂热生长的[100]取向柱状卟啉框架-11薄膜的高效金属有机框架敏化太阳能电池。
ACS Appl Mater Interfaces. 2019 Jan 23;11(3):3196-3206. doi: 10.1021/acsami.8b17807. Epub 2019 Jan 8.
5
MOF-on-MOF: Oriented Growth of Multiple Layered Thin Films of Metal-Organic Frameworks.金属有机框架上的金属有机框架：金属有机框架多层薄膜的定向生长
Angew Chem Int Ed Engl. 2019 May 20;58(21):6886-6890. doi: 10.1002/anie.201901707. Epub 2019 Apr 17.
6
Layer-by-layer fabrication of oriented porous thin films based on porphyrin-containing metal-organic frameworks.基于含卟啉的金属-有机骨架的层层制备取向多孔薄膜。
J Am Chem Soc. 2013 Oct 23;135(42):15698-701. doi: 10.1021/ja4078705. Epub 2013 Oct 15.
7
The Tuning of Optical Properties of Nanoscale MOFs-Based Thin Film through Post-Modification.通过后修饰对基于纳米级金属有机框架的薄膜光学性质的调控
Nanomaterials (Basel). 2017 Aug 29;7(9):242. doi: 10.3390/nano7090242.
8
Conformal Ultrathin Film Metal-Organic Framework Analogues: Characterization of Growth, Porosity, and Electronic Transport.共形超薄膜金属有机框架类似物：生长、孔隙率和电子传输的表征
Chem Mater. 2019 Nov 12;31(21):8977-8986. doi: 10.1021/acs.chemmater.9b03141. Epub 2019 Oct 15.
9
Porphyrin-Based MOF Thin Film on Transparent Conducting Oxide: Investigation of Growth, Porosity and Photoelectrochemical Properties.透明导电氧化物上基于卟啉的金属有机框架薄膜：生长、孔隙率及光电化学性质研究
Molecules. 2023 Aug 4;28(15):5876. doi: 10.3390/molecules28155876.
10
Improved optical quality of heteroepitaxially grown metal-organic framework thin films by modulating the crystal growth.通过调控晶体生长提高异质外延生长的金属有机框架薄膜的光学质量。
Nanoscale. 2024 Jul 25;16(29):14101-14107. doi: 10.1039/d4nr01885k.

引用本文的文献

1
Stimuli-responsive photoswitch-actinide binding: a match made in MOFs.刺激响应型光开关-锕系元素结合：金属有机框架中的完美组合。
Chem Sci. 2025 Jun 17. doi: 10.1039/d5sc03171k.
2
Special Issue "Advances in Epitaxial Materials"-Editorial Preface.特刊“外延材料进展”——编辑前言
Materials (Basel). 2020 Jun 9;13(11):2622. doi: 10.3390/ma13112622.

本文引用的文献

1
Stable Metal-Organic Frameworks with Group 4 Metals: Current Status and Trends.含第4族金属的稳定金属有机框架：现状与趋势
ACS Cent Sci. 2018 Apr 25;4(4):440-450. doi: 10.1021/acscentsci.8b00073. Epub 2018 Mar 26.
2
Metal-organic frameworks: functional luminescent and photonic materials for sensing applications.金属有机框架：用于传感应用的功能发光和光子材料。
Chem Soc Rev. 2017 Jun 6;46(11):3242-3285. doi: 10.1039/c6cs00930a.
3
Plasmon-Enhanced Photocatalytic CO(2) Conversion within Metal-Organic Frameworks under Visible Light.
在可见光下金属-有机框架内的等离子体增强光催化 CO(2)转化。
J Am Chem Soc. 2017 Jan 11;139(1):356-362. doi: 10.1021/jacs.6b11027. Epub 2016 Dec 22.
4
H S Sensors: Fumarate-Based fcu-MOF Thin Film Grown on a Capacitive Interdigitated Electrode.HS 传感器：基于富马酸的 fcu-MOF 薄膜在电容式叉指电极上生长。
Angew Chem Int Ed Engl. 2016 Dec 19;55(51):15879-15883. doi: 10.1002/anie.201608780. Epub 2016 Oct 31.
5
Crystalline, Highly Oriented MOF Thin Film: the Fabrication and Application.晶体高度取向的金属有机框架薄膜：制备与应用
Chem Rec. 2017 May;17(5):518-534. doi: 10.1002/tcr.201600109. Epub 2016 Oct 24.
6
Advanced Fabrication Method for the Preparation of MOF Thin Films: Liquid-Phase Epitaxy Approach Meets Spin Coating Method.用于 MOF 薄膜制备的先进制造方法：液相外延法与旋涂法的结合。
ACS Appl Mater Interfaces. 2016 Aug 10;8(31):20459-64. doi: 10.1021/acsami.6b04701. Epub 2016 Jul 27.
7
Photoinduced Charge-Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap?外延 MOF 薄膜中的光致电荷载流子产生：间接能带隙导致高效率？
Angew Chem Int Ed Engl. 2015 Jun 15;54(25):7441-5. doi: 10.1002/anie.201501862. Epub 2015 May 8.
8
Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination.通过自动逐层配位制备的含卟啉金属有机框架（MOF）薄膜的组装后转变
Chem Commun (Camb). 2015 Jan 4;51(1):85-8. doi: 10.1039/c4cc05727a.
9
A supermolecular building approach for the design and construction of metal-organic frameworks.超分子构筑策略在金属有机框架设计与构建中的应用
Chem Soc Rev. 2014 Aug 21;43(16):6141-72. doi: 10.1039/c4cs00135d.
10
The liquid phase epitaxy method for the construction of oriented ZIF-8 thin films with controlled growth on functionalized surfaces.液相外延法在功能化表面上构建具有可控生长取向的 ZIF-8 薄膜。
Chem Commun (Camb). 2013 Oct 3;49(86):10079-81. doi: 10.1039/c3cc45343j.