通过自动逐层配位制备的含卟啉金属有机框架（MOF）薄膜的组装后转变
Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination.
作者信息
So Monica C, Beyzavi M Hassan, Sawhney Rohan, Shekhah Osama, Eddaoudi Mohamed, Al-Juaid Salih S, Hupp Joseph T, Farha Omar K
机构信息
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
出版信息
Chem Commun (Camb). 2015 Jan 4;51(1):85-8. doi: 10.1039/c4cc05727a.
Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.
在此，我们证明了逐层（LbL）组装的柱状桨轮型金属有机框架（MOF）薄膜通过溶剂辅助连接体交换（SALE）和后组装连接体金属化转化为新的或改性的MOF的稳健性。此外，我们表明LbL合成能够提供通过其他从头合成策略无法获得的MOF。
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