The Procter and Gamble Company , Mason Business Center, 8700 Mason-Montgomery Road , Mason , Ohio 45040 , United States.
SurForce LLC , 354 South Fairview Avenue, Suite B , Goleta , California 93117-3629 , United States.
Langmuir. 2019 Dec 3;35(48):15614-15627. doi: 10.1021/acs.langmuir.9b02033. Epub 2019 Aug 16.
The adhesion force between individual human hair fibers in a crosshair geometry was measured by observing their natural bending and adhesive jumps out of contact, using optical video microscopy. The hair fibers' natural elastic responses, calibrated by measuring their natural resonant frequencies, were used to measure the forces. Using a custom-designed, automated apparatus to measure thousands of individual hair-hair contacts along millimeter length scales of hair, it was found that a broad, yet characteristic, spatially variant distribution in adhesion force is measured on the 1 to 1000 nN scale for both clean and conditioner-treated hair fibers. Comparison between the measured adhesion forces and adhesion forces modeled from the hairs' surface topography (measured using confocal laser profilometry) shows they have a good order-of-magnitude agreement and have similar breadth and shape. The agreement between the measurements and the model suggests, perhaps unsurprisingly, that hair-hair adhesion is governed, to a first approximation, by the unique surface structure of the hairs' cuticles and, therefore, the large distribution in local mean curvature at the various individual contact points along the hairs' lengths. We posit that haircare products could best control the surface properties (or at least the adhesive properties) between hairs by directly modifying the hair surface microstructure.
使用光学视频显微镜观察头发纤维在十字交叉几何形状中的自然弯曲和脱离接触时的黏附跳跃,测量了单个头发纤维之间的黏附力。通过测量头发纤维的自然共振频率,对其自然弹性响应进行校准,从而测量力。使用定制的自动化设备,沿着头发的毫米长度尺度测量数千个单个头发-头发接触点,发现对于清洁和调理处理后的头发纤维,在 1 到 1000 nN 的范围内测量到的黏附力具有广泛但具有特征的空间变化分布。将测量到的黏附力与基于头发表面形貌(使用共聚焦激光轮廓仪测量)建模的黏附力进行比较,表明它们在数量级上具有良好的一致性,并且具有相似的宽度和形状。测量值与模型之间的一致性表明,头发之间的黏附力可能主要由毛发角质层的独特表面结构决定,因此,在毛发长度上各个接触点处的局部平均曲率存在较大的分布。我们假设,护发产品可以通过直接修改头发表面的微观结构,来最好地控制头发之间的表面特性(或至少是黏附特性)。