H2-H3 相变可逆性对高能锂离子电池富镍层状氧化物阴极的影响

The Effects of Reversibility of H2-H3 Phase Transition on Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries.

作者信息

Chen Jie, Yang Huiping, Li Tianhao, Liu Chaoyang, Tong Hui, Chen Jiaxin, Liu Zengsheng, Xia Lingfeng, Chen Zhaoyong, Duan Junfei, Li Lingjun

机构信息

School of Materials Science and Engineering, Changsha University of Science and Technology, Changsha, China.

School of Metallurgy and Environment, Central South University, Changsha, China.

出版信息

Front Chem. 2019 Jul 16;7:500. doi: 10.3389/fchem.2019.00500. eCollection 2019.

Although LiNiCoMnO is attracting increasing attention on account of its high specific capacity, the moderate cycle lifetime still hinders its large-scale commercialization applications. Herein, the Ti-doped LiNiCoMnO compounds are successfully synthesized. The Li(NiCoMn)TiO sample exhibits the best electrochemical performance. Under the voltage range of 2.74.3 V, it maintains a reversible capacity of 151.01 mAh·g with the capacity retention of 83.98% after 200 cycles at 1 C. Electrochemical impedance spectroscopy (EIS) and differential capacity profiles during prolonged cycling demonstrate that the Ti doping could enhance both the abilities of electronic transition and Li ion diffusion. More importantly, Ti doping can also improve the reversibility of the H2-H3 phase transitions during charge-discharge cycles, thus improving the electrochemical performance of Ni-rich cathodes.