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磁控溅射制备的ZnO/Ag/ZnO柔性透明电极的透过率调制

The Transmittance Modulation of ZnO/Ag/ZnO Flexible Transparent Electrodes Fabricated by Magnetron Sputtering.

作者信息

Choi Dooho

机构信息

School of Advanced Materials Engineering, Dong-Eui University, 176 Eomgwangro, Busan 47340, Republic of Korea.

出版信息

J Nanosci Nanotechnol. 2020 Jan 1;20(1):379-383. doi: 10.1166/jnn.2020.17238.

Abstract

In this study, the critical role of the oxide thickness at the top and bottom layers of the ZnO/Ag/ZnO flexible transparent conductive electrodes was investigated. The peak transmittance of an 8 nm thick Ag electrode was observed at a wavelength of 320 nm, while the addition of the top and bottom ZnO layers, which serve as antireflection coating, resulted in peak shifts to the visible light wavelengths with a simultaneous improvement in the transmittance as well as the spectral uniformity. By independently varying the thickness values of the top and bottom ZnO layers, it was determined that the thickness variation of the top ZnO layer had a dominant effect in the transmittance, while a lesser but still significant contribution was obtained by varying the thickness of the bottom ZnO layer. At the optimized values of thickness for the top and bottom ZnO layers, the ZnO/Ag/ZnO electrode exhibits peak and average transmittance of 97.2% and 89.7%, respectively, along with a sheet resistance of 7.8 Ω/sq, with a corresponding Haacke's figure of merit ( = /) of 0.043, which exceeds that of the conventional indium-tin-oxide electrodes.

摘要

在本研究中,对ZnO/Ag/ZnO柔性透明导电电极顶层和底层氧化物厚度的关键作用进行了研究。观察到8nm厚的Ag电极在波长320nm处有峰值透过率,而作为抗反射涂层的顶层和底层ZnO层的添加,导致峰值向可见光波长移动,同时透过率和光谱均匀性得到改善。通过独立改变顶层和底层ZnO层的厚度值,确定顶层ZnO层的厚度变化对透过率有主导作用,而改变底层ZnO层的厚度也有较小但仍显著的贡献。在顶层和底层ZnO层的优化厚度值下,ZnO/Ag/ZnO电极的峰值透过率和平均透过率分别为97.2%和89.7%,方块电阻为7.8Ω/sq,相应的哈克品质因数(=/)为0.043,超过了传统的铟锡氧化物电极。

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